Thermodynamics of irreversible electrochemical phenomena

Irreversible Thermodynamics

There are alternative sets of postulates which yield entirely equivalent results for several important theories. In such cases the choice of a particular set of postulates may be based upon mathematical simplicity, close relationship to experiments or to the nature of the theory, or merely personal taste. While the postulate of conservation of energy is usually presented in similar form for the...

Basics of Irreversible Thermodynamics

Weakly Nonlocal Irreversible Thermodynamics

Weakly nonlocal thermodynamic theories are critically revisited. A relocalized, irreversible thermodynamic theory of nonlocal phenomena is given, based on a modified form of the entropy current and new kind of internal variables, the so called current multipliers. The treatment is restricted to deal with nonlocality connected to dynamic thermodynamic variables. Several classical equations are d...

Weakly Nonlocal Irreversible Thermodynamics

Weakly nonlocal thermodynamic theories are critically revisited. The irreversible thermodynamic theory of nonlocal phenomena is given, based on a modified form of the entropy current. Several classical equations are derived , including Guyer-Krumhansl, Ginzburg-Landau and Cahn-Hilliard type equations.

Thermoelastkity and Irreversible Thermodynamics

A unified treatment is presented of thermoelasticity by application and further developments of the methods of irreversible thermodynamics. The concept of generalized free energy introduced in a previous publication plays the role of a " thermoelastic potential " and is used along with a new definition of the dissipation function in terms of the time derivative of an entropy displacement. The g...